航运业在支撑全球贸易的同时,伴随大量SOx、NOx和CO2排放,带来严峻的环境与气候挑战。本文结合最新数据与政策,综述船舶尾气减排技术及发展趋势。脱硫方面,分析了低硫燃油替代、开环/闭环及混合式海水脱硫、电解脱硫等工艺的机理与适用性;脱硝方面,比较了选择性催化还原(SCR)、废气再循环(EGR)及吸附法的性能差异与限制;脱硫脱硝一体化方面,探讨了臭氧氧化吸收法和低温等离子体法的应用特点;脱碳方面,评估了液化天然气、绿色甲醇、氨、氢等清洁燃料,以及燃烧前、富氧燃烧与燃烧后碳捕集及利用(CCUS)技术的可行性。结合IMO最新温室气体减排战略,指出燃料多元化、尾气处理系统集成化及碳捕集利用优化将是实现航运业绿色低碳转型的关键方向。
While the shipping industry underpins global trade, it is also a major source of SOx, NOx, and CO2 emissions. This paper reviews current ship exhaust emission reduction technologies and development trends. For desulfurization, the applicability of low-sulfur fuel substitution, open/closed-loop and hybrid seawater scrubbing, and electrochemical desulfurization are analyzed. For denitrification, the performance differences of selective catalytic reduction (SCR), exhaust gas recirculation (EGR), and adsorption methods are compared. For integrated SOx and NOx removal, the principles and characteristics of ozone oxidation-absorption and low-temperature plasma methods are discussed. For decarbonization, the feasibility of clean fuels such as liquefied natural gas (LNG), green methanol, ammonia, and hydrogen, as well as carbon capture and utilization (CCUS) are assessed. Based on the IMO's latest greenhouse gas reduction strategy, fuel diversification, integrated exhaust gas treatment systems, and optimized CCUS will be key to achieving a green and low-carbon transition in the shipping sector.
2026,48(5): 170-176 收稿日期:2025-5-14
DOI:10.3404/j.issn.1672-7649.2026.05.027
分类号:U676.3
基金项目:浙江省“领雁”计划项目(2023C03156)
作者简介:刘含笑(1987-),男,硕士,高级工程师,研究方向为工业烟气治理及双碳技术研发
参考文献:
[1] HUAXIA. Cargo throughput at China's ports logs solid growth in Jan-April [Z]. xinhuanet. 2025: 06-01.
[2] 关毅鹏, 李晓明, 张召才, 等. 海水脱硫应用现状与研究进展[J]. 中国电力, 2012, 45(2): 40-44
GUAN Y P, LI X M, ZHANG Z C, et al. Application and research progress of seawater desulfurization technology[J]. Electric Power, 2012, 45(2): 40-44
[3] LI X, YIN H, QU Z. Research progress of ship exhaust gas treatment technology[C]// Proceedings of the 2021 6th International Conference on Transportation Information and Safety (ICTIS), 2021, 10: 22–24.
[4] XIAOLI MAO Z M, BRYAN COMER, TOM DECKER. Greenhouse gas emissions and air pollution from global shipping, 2016–2023 [J]. The Internationa Council on Clean Transportation, 2025. 4.
[5] IMO. Draft regulations will set mandatory marine fuel standard and GHG emissions pricing for shipping to address climate change. [J/OL]. 2025.4.
[6] SARBANHA A-A, LARACHI F, TAGHAVI S-M, et al. Mitigation of ship emissions: overview of recent trends[J]. Industrial & Engineering Chemistry Research, 2023, 62(4): 1707-1724
[7] 李军伟, 张晓红, 张新民. 我国船舶大气污染物排放及控制研究[J]. 资源节约与环保, 2020(10): 94-97
[8] LUNDE HERMANSSON A, HASSELLöV I-M, GRöNHOLM T, et al. Strong economic incentives of ship scrubbers promoting pollution[J]. Nature Sustainability, 2024, 7(6): 812-822
[9] SINGH A, SHANTHAKUMAR S. Economic and legal impact of 2020 sulphur limit under annex VI, MARPOL [J]. European Energy and Environmental Law Review, 2022: 241-257.
[10] GORDON S. Green Technology Tracker: 41% of tonnage ordered in 1H 2024 alternative fuelled [J/OL]. Clarksons Research, 2024.
[11] KOCK F. DNV GL study looks at challenges in scrubber operations [J/OL]. 2020.2.
[12] 刘国臣, 王廷勇, 赵超, 等. 船舶废气脱硫废水处理技术应用现状[C]//2019中国环境科学学会科学技术年会, 2019.
[13] 邓振兴. 船舶烟气旋流雾化脱硫系统的工艺设计与试验研究 [D]. 广州: 华南理工大学, 2020.
[14] 董伟. 基于NaOH的船舶废气洗涤效率实验研究 [D]. 哈尔滨: 哈尔滨工程大学, 2013.
[15] ZHAO J, YANG Y, LI H, et al. The application of two-phase composite absorbent systems consisting of BAD and seawater resources in the wet treatment of ship exhaust gas[J]. iScience, 2023, 26(4): 106472
[16] 姚聪颖, 陶汉中, 张红, 等. 基于氢氧化钠法的船舶废气脱硫分析[C]//《环境工程》2019年全国学术年会, 2019.
[17] 中国产业园研究院. 2024-2029 年中国船舶节能降碳行业市场深度调研及投资策略预测报告 [R]. 2025.
[18] 张欢, 钟鹭斌, 陈进生, 等. 船舶尾气脱硫脱硝技术研究进展[J]. 化工进展, 2016, 35(11): 3650-3657
ZHANG H, ZHONG L B, CHEN J S, et al. Review on desulfurization and denitration technologies for ship exhaust gas treatment[J]. Chemical Industry and Engineering Progress, 2016, 35(11): 3650-3657
[19] MYŚKóW J, BORKOWSKI T, BLUDSZUWEIT M, et al. Marine engine exhaust gas emission aftertreatment system concept[J]. Journal of KONES, 2011, 18: 307-315
[20] USHAKOV S, STENERSEN D, EINANG P M, et al. Meeting future emission regulation at sea by combining low-pressure EGR and seawater scrubbing[J]. Journal of Marine Science Technology, 2020, 25(2): 482-497
[21] ZANNIS T C, KATSANIS J S, CHRISTOPOULOS G P, et al. Marine exhaust gas treatment systems for compliance with the IMO 2020 global sulfur cap and tier III NOx limits: A Review [J]. Energies, 2022, 15(10): 3638.
[22] 刘博, 吴朝晖, 钱跃华. 船用低速发动机技术现状及发展趋势 [N]. 中国船舶报, 2020-06-10.
[23] AGARWAL D, SINGH S K, AGARWAL A K. Effect of Exhaust Gas Recirculation (EGR) on performance, emissions, deposits and durability of a constant speed compression ignition engine[J]. Applied Energy, 2011, 88(8): 2900-2907
[24] 于志日, 李楠, 安勋, 等. 氮氧化物吸附剂的研究进展[J]. 辽宁化工, 2023, 52(3): 433-435
YU Z R, LI N, AN X, et al. Research progress of nitrogen oxide adsorbents[J]. Liaoning Chemical Industry, 2023, 52(3): 433-435
[25] 李娟娟. 吸附脱除低浓度一氧化氮的研究 [D]. 大连: 大连理工大学, 2017.
[26] 喻文烯. 等离子体脱硫脱硝及其用于船舶柴油机尾气处理的研究[D]. 武汉: 武汉纺织大学, 2013.
[27] FANG P, TANG Z, CHEN X, et al. Simultaneous removal of NOx and SO2 through a simple process using a composite absorbent [J]. Sustainability, 2018, 10(12): 4350.
[28] 冉佳. 臭氧氧化结合碱液吸收法脱硫脱硝过程研究 [D]. 北京: 中国石油大学, 2020.
[29] 杨国华, 胡文佳, 周江华, 等. 船舶尾气臭氧氧化-海水吸收的脱硫脱硝新工艺研究[J]. 内燃机学报, 2008, 26(3): 278-282
YANG G H, HU W J, ZHOU J H, et al. Simultaneous removal of SO2 and NOx from ship exhaust through a combination of Ozone oxidation and sea water scrubbing[J]. Transactions of CSICE, 2008, 26(3): 278-282
[30] 吴祖良, 高翔, 李济吾, 等. 电晕放电自由基簇射同时脱硫脱硝反应特性研究[J]. 高校化学工程学报, 2008(2): 325-331
WU Z L, GAO X, LI J W, et al. Study on the reactive characteristics of simultaneous removal of SO2 and NOx by corona discharge radical shower system[J]. Journal of Chemical Engineering of Chinese Universities, 2008(2): 325-331
[31] 骆嘉钦. 低温等离子体船舶尾气脱硫脱硝研究 [D]. 西安: 西北大学, 2021.
[32] GHAFORIAN MASODZADEH P, ÖLçER A I, BALLINI F, et al. A review on barriers to and solutions for shipping decarbonization: What could be the best policy approach for shipping decarbonization?[J]. Marine Pollution Bulletin, 2022, 184: 114008
[33] 向轶, 吕文豪, 杨国华, 等. 基于湿法脱硫工艺的船舶尾气处理系统设计分析[J]. 四川环境, 2020, 39(3): 97-103
XIANG Y, LV W H, YANG G H, et al. Design and analysis of marine exhaust gas treatment system based on wet desulfurization process[J]. Sichuan Environment, 2020, 39(3): 97-103
[34] 张斌. 脱硫塔在船舶工程中的应用[J]. 科技风, 2020(8): 137
[35] INAL O B, ZINCIR B, DENIZ C. Investigation on the decarbonization of shipping: an approach to hydrogen and ammonia[J]. International Journal of Hydrogen Energy, 2022, 47(45): 19888-19900
[36] 卢奇秀. 绿色甲醇船舶“失宠”? [N]. 中国能源报, 2025-03-17.
[37] 彭传圣. 我国航运脱碳挑战及路径选择[J]. 中国海事, 2023(6): 24-29
PENG C S. Challenges and path of china's shipping decarbonization[J]. China Maritime Safety, 2023(6): 24-29
[38] 刘易明, 王甫, 王珺, 等. 燃料电池船舶应用形式及其关键技术[J]. 船舶工程, 2021, 43(3): 18-26
LIU Y M, WANG F, WANG J , et al. Application form and its key technology of fuel cell ship[J]. Ship Engineering, 2021, 43(3): 18-26
[39] 丁先, 李汪繁, 马达夫, 等. 生物质锅炉富氧燃烧技术研究进展[J]. 动力工程学报, 2024, 44(2): 157-167
DING X, LI W F, MA D F, et al. Research progress on oxygen-enriched combustion technology in biomass boiler[J]. Journal of Chinese Society of Power Engineering, 2024, 44(2): 157-167
[40] 孙化栋, 仝永臣, 李岩. CCUS技术在船舶上的应用进展研究[J]. 青岛远洋船员职业学院学报, 2021, 42(4): 21-26
SUN H D, TONG Y C, LI Y. Research on the application of CCUS technology on ship[J]. Journal of Qingdao Ocean Shipping Mariners College, 2021, 42(4): 21-26
[41] 代小佩. 让二氧化碳“无处可遁”——全球首套全流程船舶碳捕集系统研发纪实 [N]. 科技日报, 2025–03–02.
[42] 卢明剑, 董胜节, 严新平, 等. 船舶碳捕集、利用与封存技术综述[J]. 交通运输工程学报, 2024, 24(2): 1-19
LU M J, DONG S J, YAN X P, et al. Review on ship-based carbon capture,utilization and sequestration technology[J]. Journal of Traffic and Transportation Engineering, 2024, 24(2): 1-19
[43] 王雪振. 浅议船舶二氧化碳灭火站的使用和灭火[J]. 中国设备工程, 2024(17): 244-246
[44] 高进, 江山, 瞿杨, 等. “双碳”目标下天然气净化厂碳资源回收工艺及应用展望——以中国石油西南油气田公司为例[J]. 天然气技术与经济, 2024, 18(2): 39-44
GAO J, JIANG S, QV Y, et al. Recycling carbon resources in natural-gas purification plants under the carbon-peak and carbon-neutrality goal:an example from petrochina southwest oil&gasfield company[J]. Natural Gas Technology and Economy, 2024, 18(2): 39-44
[45] AYYAR A S, AREGAWI D T, PETERSEN A R, et al. Carbon dioxide-mediated desalination[J]. Journal of the American Chemical Society, 2023, 145(6): 3499-3506
[46] WERMUTH N, LACKNER M, BARNSTEDT K D, et al. The HyMethShip Project: innovative emission free propulsion for maritime applications[C]//Proceedings of the 17 FAD-Konferenz Herausforderung-Abgasnachbehandlung, 2019.
[47] 跨大西洋-这艘双燃料甲醇运输船完成净零排放航行 [J]. 中国船检, 2023, (3): 97.
[48] LINDBERG A. Excess Heat Use Cases in theÖrnsköldsvik Municipality: Investigating the possibilities to use greenhouses, aquaculture, or other systems to use excess heat from the coming FlagshipONE factory [J]. A Lindberg, 2024.
[49] ILIUTA I, LARACHI F, FONTAINE F-G. Conversion of CO2 from the energy systems on-board ships via catalytic cycloaddition to styrene oxide: modeling and numerical simulation[J]. Industrial Engineering Chemistry Research, 2022, 61(47): 17275-17296
[50] ZHANG C, ZHU J, GUO H, et al. Technical requirements for 2023 IMO GHG strategy[J]. Sustainability, 2024, 16(7): 2766
[51] LIU H, MAO Z, LI X. Analysis of international shipping emissions reduction policy and China's participation [J]. Frontiers in Marine Science, 2023, 10.